Traditionally, as in decades ago, it was actually considered somewhat vulgar to use terms like "male" and "female" to refer to human beings. The term "woman CEO" would have been preferred for that reason. Somehow I like the aesthetic of "woman CEO" over "female CEO" for the same reason. It seems more dignified and humanistic.
Hence why I tend to use "female" and "male." Mankind is not separate from the animal kingdom. Although I suppose male human and female human are the least ambiguous.
Even these days, many people have a problem with "female". Some people with particularly unsavoury views of women have a particular tendency to use it.